李志宝

中国科学院过程工程研究所

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  • 李志宝
  • 研究员
  • 北京市海淀区中关村北二街1号

李志宝研究员,1962年出生,博士生导师,湿法冶金与结晶分离课题组组长,《Hydrometallurgy》 国际杂志编委。1998年6月获清华大学化学工程博士学位。2006年6月获加拿大 McGill大学冶金和金属材料工程博士学位。1999年-2001年在加拿大Ottawa大学化学工程系做博士后研究,2001年至2002年以在加拿大McGill大学冶金和金属材料工程系做博士后研究。现任中国科学院过程工程研究所研究员。主要研究领域涉及:化学工程,湿法冶金,电解质溶液热力学,矿产资源高效利用,沉淀结晶高效分离技术,结晶材料制备工程,界面现象和统计力学。已发表杂志学术论文100多篇。曾获中国科学院科技进步三等奖,1997年在清华大学读博士期间获得学术新人候选人奖,2002至2004年连续三年获得McGill大学Rugh William Stewart Scholarship奖学金。

研究领域:

1. 过程湿法冶金

湿法冶金是将矿石、经选矿富集的精矿或其他原料与水溶液或者其他液体相接触,通过化学反应等,使原料中所含有的金属转 入液相,再对液相中所含有各种有用金属进行分离富集,最后以金属或者其他化合物的形式加以回收的方法。湿法冶金以无机化学和物理化学等理论学科为基础,主 要应用领域包括浸取,富集和净化,金属回收。本课题组研究方向是低品位矿物浸取包括低品位铝土矿和钼精矿等,浸取采用包括原位浸取、堆浸取、和容器浸取等 方式,利用酸、碱、加压手段,将铝土矿、辉钼矿中的硅脱除,使铝土矿中的铝硅比由4:1~5:1提高到10:1以上,使辉钼矿纯度提高到98%。

2. 工业沉淀与结晶

结晶在制造业中如化工、制药和食品等工业领域中也有广泛的应用。结晶操作不仅能够从溶液中取得固体溶质,而且能够实现溶质与杂质的分离,借以提高产品的纯度。它具有成本低,操作方便,产品性质多样化的特点。沉淀结晶,又称快速结晶,属于结晶过程中的一种。结晶沉淀是化学工艺中的基本过程,化学工业采用结晶沉淀生产的产品占到总固体产品的70%。结晶沉淀由于操作条件上的低温低能耗和产品上的纯度高,常用于分离和净化。操作条件决定着结晶产品的性质包括纯度、过滤性能、流动性、反应性能等,要得到性能优异的产品就需要掌握结晶过程中过饱和度的控制、成核、晶体生长、陈化以及二次成核等方面的知识与方法。本课题研究的结晶过程包括碳酸镁水合物的沉淀过程及氯化铵的结晶过程,通过建立沉淀结晶过程的数学模型和结晶器流体流动模 型,提出一套用于反应结晶器设计、放大和优化的方法。

3.复杂体系的溶液热力学和结晶过程的非平衡热力学

溶解和结晶过程广泛存在于各个领域,它们都涉及包含固体材料的复杂体系。这类复杂体系的平衡与非平衡热力学问题是工艺设计开发和模拟优化的基础,也是当前的研究热点,但由于对于界面处的传递过程理解不够深入,目前建立具有工程应用价值的溶解或结晶速率模型都遇到了很大的困难。一般,固液体系表面生长和溶解反应的速率方程可写成形式,时为平衡态,时为固体表面生长状态,时为固体溶解状态。第一种情况为平衡热力学,后两种情况为非平衡热力学的研究范畴。课题组利用化工热力学模型(如Pitzer,Electrolyte-NRTL,UNIFAC等)和化工软件(如AspenPlus,OLI software), 对实验室测得的少量实验数据进行处理,得到相关的参数,从而计算出过程开发中大量的有用数据;建立了原创性表面张力模型;研究含离子液体体系热力学性质,并建立离子液体性质的热力学模型;通过非平衡热力学分析建立了描述晶体生长的动力学模型。

学术任职情况

国际期刊《Hydrometallurgy》杂志国际编委中国科学院过程工程研究所学位委员会委员中国科学院过程工程研究所工程技术委员会委员国家留学基金委评审专家国家自然科学基金委评审专家

可转化成果

盐湖卤水制备高纯氧化镁节能新技术菱镁矿制备高活性高纯度氧化镁绿色新工艺氨基乙酸生产绿色新工艺(无甲醇)乙醇脱水节能新工艺钛白粉副产七水硫酸亚铁制备氧化铁红

承担项目情况:

蛇纹石中硅镁分离及固定CO2的基础热力学研究, 国家自然科学基金面上项目, 2015-2017盐湖MgCl2在混合溶剂体系中相平衡及其在Z-N型催化剂载体制备中应用, 国家联合基金培育项目, 2015-2017纯碱工业节能减排工程联合实验室,合作单位:山东金晶集团,2015-2018高铬钒渣亚熔盐法钒铬高效提取分离与污染控制, 973项目(课题负责人),2013-2017高硅一水硬铝石在浓NaOH溶液中高压相平衡测定和模拟,国家自然科学基金,2011-2014利用卤水氯化镁固定CO2的物理化学研究,国家自然科学基金,2012-2013碳铵循环法生产高纯氧化镁工业化节能关键技术研究,院地合作项目,2011-2014以氯化镁和ADC发泡剂副产十水碳酸钠为原料年产2.5万吨工业化实验研究,青海科技厅重大项目,2010-2013海盐卤水综合利用制备高纯氧化镁节能新工艺研究, 江苏省科技支撑工业项目,2008-2010

国际期刊论文(目前已发表一百多篇论文,其中AIChE Journal 8篇,Industrial & Engineering Chemistry Research 25篇)

2018-2019年

1.Wang, QX., Li, ZB. A modified Solvay process with low temperature calcination of NaHCO3 using monoethanolamine: Solubility determination and thermodynamic modeling. AIChE J. 2019 (Just Accepted).

2.Zeng, XZ., Zeng Y., Li, ZB. Measurements and modeling of the phase equilibria in AlCl3 + NaCl + CaCl2 + H2O and AlCl3 + CaCl2 + NH4Cl + H2O Systems.J. Chem Eng Data. 2019; 64: 895-904.

3.Wang, QX., Li, ZB. Solubility determination and thermodynamic modeling for he system NaCl-NH4Cl-Diethanolamine-H2O. J. Chem Eng Data. 2019; 64: 895-904.

4.Jiang. SF., Zhang. YD., Li, ZB. A New Industrial Process of NaHCO3 and Its Crystallization Kinetics by Using the Common Ion Effect of Na2CO3. Chem. Eng. J. 2019;60:740-749.

5.Ansari ZH., Zeng Y., Demopoulos G., Li, ZB. Nucleation kinetics of MgCl2–ethanol adduct for the supported Ziegler–Natta catalysts with a thermodynamic approach. J Cryst Growth. 2019; 494: 44-52.

6.Zhou J., Zeng Y., Demopoulos G., Li CX., Li, ZB. Phase Transition of FeSO4·7H2O to FeSO4·H2O in the H2SO4–HCl–H2O System by Modeling Solubility. ACS Sus. Chem. Eng. 2018;6(2):2207–2219.

2017年

7.Zhang Y, Li Z, Zeng Y, Demopoulos GP. A Green Process for Recovery of H2SO4 and Fe2O3 from FeSO4·7H2O by Modeling Phase Equilibrium of the Fe(П)?SO42??H+?Cl? System. AIChE J. 2017;63(10):4549-4563.

8.Zhang Y, Zhou J, Li Z. Solubility of FeSO4·7H2O in the H2SO4–Ti(SO4)2–H2O, H2SO4–MgSO4–H2O, and HCl–H2O Systems from 278 to 313 K. J. Chem. Eng. Data. 2017;62(3):973–979.

9.Ansari ZH, Li Z. Solid–Liquid Equilibria for the Glycine–Alcohol–NaCl–H2O System. J. Chem. Eng. Data. 2017;62(10):3551–3560.

10.Zhou J, Zeng Y, Demopoulos GP, Li C, Li Z. Solubility of NaHCO3 and NH4HCO3 in the Relevant Media and Prediction of High-Pressure Phase Equilibria for the NH3–CO2–NaCl–H2O System. J. Chem. Eng. Data.

11.Ansari ZH, Zeng Y, Zhang Y, Demopoulos GP, Li Z. Modeling of glycine solubility in aqueous HCl–MgCl2 system and its application in phase transition of glycine by changing media and supersaturation. Journal of Crystal Growth. 2017;467:116-125

2016年

12.Ziaul Haque Ansari, Zhibao Li. Solubilities and Modeling of Glycine in Mixed NaCl–MgCl2 Solutions in a Highly Concentrated Region. Journal of Chemical & Engineering Data, 2016, 61 (10):3488–3497

13.Yan Zhang, Edouard Asselin, Zhibao Li. Solubility measurement and chemical modeling of M MgSO4·7H2O in the Ti(SO4)2–H2SO4–H2O system. Journal of Chemical & Engineering Data, 2016, 61: 2363-2370.

14.Yan Zhang, Zhibao Li, Edouard Asselin. Determination and chemical modeling of the solubility of FeSO4·7H2O in the Ti(SO4)2-H2SO4-H2O system. Journal of Chemical Thermodynamics, 2016, 102: 219-227. 102.

15.Yan Zhang, Edouard Asselin, Zhibao Li. Laboratory and pilot scale studies of potassium extraction from K-feldspar decomposition with CaCl2 and CaCO3. Journal of Chemical Engineering of Japan, 2016, 49: 111-119. 102.

16.Yan Zeng, Zhibao Li, George P. Demopoulos Process for Glycine Production by Antisolvent Crystallization Using Its Phase Equilibria in the Ethylene Glycol–NH4Cl–Water System. Industrial & Engineering Chemistry Research, 2016, 55 (8):2426–2437.

17.Lanmu Zeng, Zhibao Li, Xiaolin Wang. Determination and Modeling of MgCl2 Solubility in Methanol, Ethanol, 2-Propanol, and Their Mixtures from 283 to 343 K. Journal of Chemical & Engineering Data, 2016, 61: 797-805.

2015年

18.Junfeng Wang, Zhibao Li, Ah-Hyung Alissa Park, Camille Petit. Thermodynamic and Kinetic Studies of the MgCl2-NH4Cl-NH3-H2O System for the Production of High Purity MgO from Calcined Low-Grade Magnesite. AIChE Journal 2015, 61(6): 1933-1946.

19.Lanmu Zeng, Zhibao Li. A new process for fuel ethanol dehydration based on modeling the phase equilibria of the anhydrous MgCl2+ethanol+water system. AIChE Journal 2015, 61(2): 664-676.

20.Yan Zeng, Zhibao Li, Edouard Asselin. Modeling Phase Equilibria for the Glycine–NH4Cl–Methanol–Water System and Its Application for the Industrial Monochloroacetic Acid Process. Industrial & Engineering Chemistry Research 2015, 54 (13), 3488–3497.

21.Yan Zhang, Zhibao Li. Vapor–Liquid Equilibria of the FeSO4–Fe2(SO4)3–H2SO4–H2O System at (30, 60, 90, and 101.3) kPa. Journal of Chemical & Engineering Data 2015, 60 (3): 947-954.

2014年

22.Yan Zeng, Zhibao Li, George P. Demopoulos. Phase equilibria for the glycine–methanol–NH4Cl–H2O System. Industrial & Engineering Chemistry Research 2014, 53 (43), 16864–16872.

23.Geng Li, Yan Zhang, Edouard Asselin, Zhibao Li. Vapor-liquid equilibria for the ZnSO4-H2SO4-H2O and MgSO4-H2SO4-H2O systems at (30, 60, 90, and 101.3) kPa. Journal of Chemical & Engineering Data 2014, 2014, 59 (11): 3449-3460.

24.Lanmu Zeng, Zhibao Li. Solubility of dicalcium silicate in the NaOH–NaAl(OH)4–Na2CO3 solutions: Determination and prediction. Hydrometallurgy 2014, 147-148: 127-133.

25.Geng Li, Edouard Asselin, Zhibao Li. Process simulation of sulfuric acid recovery by azeotropic distillation: Vapor–liquid equilibria and thermodynamic modeling. Industrial & Engineering Chemistry Research 2014, 53(29): 11794?11804.

26.Yan Zeng, Yan Zhang, Zhibao Li, George P. Demopoulos. Measurement and chemical modeling of the solubility of Na2SiO3·9H2O and Na2SiO3 in concentrated NaOH solution from 288 to 353 K. Industrial & Engineering Chemistry Research 2014, 53(23): 9949-9958.

27.Wencheng Gao, Jiankang Wen, Zhibao Li. Dissolution kinetics of magnesium from calcined serpentine in NH4Cl solution. Industrial & Engineering Chemistry Research 2014, 53(19), 7947-7955.

28.Yan Zeng, Zhibao Li, George P. Demopoulos. Determination and modeling of the solubility of Na2SiO3·9H2O in the NaCl–KCl–H2O system. Journal of Chemical & Engineering Data 2014, 59(4): 1264-1272.

2013年

29.Wencheng Gao, Zhibao Li, Edouard Asselin. Solubility of AlCl3·6H2O in the Fe(II) + Mg + Ca + K + Cl + H2O system and its salting-out crystallization with FeCl2. Industrial & Engineering Chemistry Research 2013, 52: 14282–14290.

30.Lanmu Zeng, Zhibao Li. Dissolution behavior of aluminum, silicon, and iron of diaspore concentrate in NaOH?NaAl(OH)4 solutions at elevated temperature. Industrial& Engineering Chemistry Research 2013, 52(51): 18429-18439.

31.Dehua Xu, Huiquan Li, Zhibao Li. Determination and modeling of isobaric vapor–liquid equilibria for the methylcarbamate + methyl-N-phenyl carbamate system at different pressures. Journal of Chemical & Engineering Data 2013, 58(11): 3110-3117.

32.Wenting Cheng, Zhibao Li, Fangqin Cheng. Solubility of Li2CO3 in Na–K–Li–Cl brines from 20 to 90 °C. Journal of Chemical Thermodynamics 2013, 67: 74–8.

33.Juanjuan Zhang, He Zhao, Hongbin Cao, Heping Li, Zhibao Li. Removal of Cd2+ from water by Friedel’s salt (FS:3CaO·A12O3·CaCl2·10H2O): Sorption characteristics and mechanisms. Journal of Environmental Sciences 2013, 25(9): 1719–1725.

34.Wencheng Gao, Zhibao Li. A practical approach to produce Mg-Al spinel based on the modeling of phase equilibria for NH4Cl-MgCl2-AlCl3-H2O system. AIChE Journal 2013, 59: 1855-1867.

35.Geng Li, Zhibao Li. Measurement and modeling of vapor–liquid equilibria for the octane + sulfuric acid + water + ethanol system. Journal of Chemical & Engineering Data 2013, 58(7): 2044-2050.

36.Junfeng Wang, Zhibao Li. Measurement and modeling of vapor–liquid equilibria for systems containing alcohols, water, and imidazolium-based phosphate ionic liquids. Journal of Chemical & Engineering Data 2013, 58(6): 1641?1649.

37.Geng Li, ZhibaoLi, Edouard Asselin. Determination and modeling of vapor–liquid equilibria for the sulfuricacid + water + butyl acetate + ethanol system. Industrial& Engineering Chemistry Research 2013, 52: 3481-3489.

38.Feng Liu, Pengge Ning, Hongbin Cao, Zhibao Li, Yi Zhang. Solubilities of NH4VO3 in the NH3-NH4+SO42-+Cl+H2O system and modeling by the Bromley-Zemaitis equation. Journal of Chemical & Engineering Data 2013, 58: 1321-1328.

2012年

39.Ping Tian, Pengge Ning, Hongbin Cao, Zhibao Li. Determination and modeling of solubility for CaSO4·2H2O-NH4+Cl-SO42-NO3??H2O system. Journal of Chemical & Engineering Data 2012, 57: 3664-3671.

40.Daoguang Wang, Zhibao Li. Gas-liquid reactive crystallization kinetics of hydromagnesite in the MgCl2-CO2-NH3-H2O system: Its potential in CO2 sequestration. Industrial & Engineering Chemistry Research 2012, 51(50), 16299-16310.

41.Lanmu Zeng, Zhibao Li. Solubility and modeling of sodium aluminosilicate in NaOH–NaAl(OH)4 solutions and its application to desilication. Industrial & Engineering Chemistry Research 2012, 51(46): 15193-15206.

42.Geng Li, Zhibao Li. Determination and prediction of vapor–liquid equilibria for a system containing water + butyl acetate + cyclohexane + ethanol. Journal of Chemical & Engineering Data 2012, 57(9): 2543-2548.

43.Junfeng Wang, Zhibao Li. Crystallization and agglomeration kinetics of hydromagnesite in the reactive system MgCl2-Na2CO3-NaOH-H2O. Industrial & Engineering Chemistry Research 2012, 51(23): 7874-7883.

44.Wencheng Gao, Zhibao Li. Determination and chemical modeling of phase equilibria for the glycine-KCl-NaCl-H2O system and its application to produce crystals with anticaking characteristics. Industrial & Engineering Chemistry Research 2012, 51(24): 8315-8325.

45.Daoguang Wang, Zhibao Li. Chemical modeling of nesquehonite solubility in Li + Na + K + NH4 + Mg + Cl + H2O system with a speciation-based approach. Chinese Journal of Chemical Engineering 2012, 20(2): 267-276.

46.Daoguang Wang, Zhibao Li. Kinetic analysis for crystal growth rate of NH4Cl in the NaCl-MgCl2-H2O system with a thermodynamic approach. AIChE Journal 2012, 58(3): 914-924.

47.Daoguang Wang, Zhibao Li. Study of crystallization kinetics of ammonium carnallite and ammonium chloride in the NH4Cl-MgCl2-H2O system. Industrial & Engineering Chemistry Research 2012, 51(5): 2397-2406.

48.Shunping Sun, Junfeng Wang, Zhibao Li. Solubility and self-consistent modeling of aniline hydrochloride in H-Mg-Na-Ca-Al-Cl-H2O system at temperature range of 288?348 K. Industrial & Engineering Chemistry Research 2012, 51(9): 3783-3790.

49.Wencheng Gao, Zhibao Li. Solubility and KSP of Mg4Al2(OH)14·3H2O at the various ionic strengths. Hydrometallurgy 2012, 117–118: 36–46.

50.Shunping Sun, Zhibao Li. Experimental measurement and modeling of aniline hydrochloride solubility in water, methanol, ethanol, propan-1-ol, and their mixed systems. Journal of Chemical & Engineering Data 2012, 57(1): 219–226.

2011年

51.Daoguang Wang, Zhibao Li. Modeling solid-liquid equilibrium of NH4Cl–MgCl2–H2O system and its application to recovery of NH4Cl in MgO production. AIChE Journal 2011, 57(6): 1595-1606.

52.Jiayu Ma, Zhibao Li, Qinggui Xiao. A new process for Al2O3 production from low-grade diasporic bauxite based on reactive silica dissolution and stabilization in NaOH–NaAl(OH)4 media. AIChE Journal 2011, 58(7): 2180-2191.

53.Junfeng Wang, Shunping Sun, Zhibao Li. Modeling of solid–liquid equilibrium for the [HAE]Cl–MgCl2–H2O system. Industrial & Engineering Chemistry Research 2011, 50(13): 8314–8322.

54.Yan Zhang, Zhibao Li. Effects of cooling rate, saturation temperature, and solvent on the metastable zone width of triethanolamine hydrochloride. Industrial & Engineering Chemistry Research 2011, 50(10): 6375–6381.

55.Jiayu Ma, Kunming Zhai, Zhibao Li. Desilication of synthetic Bayer liquor with calcium sulfate dihydrate: Kinetics and modelling. Hydrometallurgy 2011, 107(1–2): 48-55.

2010年

56.Junfeng Wang, Zhibao Li, Chunxi Li, Zihao Wang. Density prediction of ionic liquids at different temperatures and pressures using a group contribution equation of state based on electrolyte perturbation theory. Industrial & Engineering Chemistry Research 2010, 49(9): 4420–4425.

57.Junfeng Wang, Daoguang Wang, Zhibao Li, Fan Zhang. Vapor pressure measurement and correlation or prediction for water, 1-Propanol, 2-Propanol, and their binary mixtures with [MMIM][DMP] ionic liquid. Journal of Chemical & Engineering Data 2010, 55(11): 4872–4877.

58.Wenting Cheng, Zhibao Li. Controlled supersaturation precipitation of hydromagnesite for the MgCl2-Na2CO3 system at elevated temperatures: chemical modeling and experiment. Industrial & Engineering Chemistry Research 2010, 49: 1964-1974.

59.Jiayu Ma, Zhibao Li. Chemical equilibrium modeling and experimental measurement of solubility for friedel’s salt in the Na-OH-Cl-NO3-H2O systems up to 200 C. Industrial & Engineering Chemistry Research 2010, 49: 8949-8958.

60.Yan Zhang, Zhibao Li. Solubilities of triethanolamine hydrochloride ionic liquid in aqueous hydrochloric acid solutions with concentrations from (0 to 8.37) mol/kg. Journal of Chemical & Engineering Data 2010, 55: 4434-4439.

61.Hongqing Wang, Daoguang Wang, Zhibao Li, George P. Demopoulos. Solubility and scale prevention of gypsum in transportation pipes of well brine with salinities up to 5 M at temperature range of 278 to 298 K. Desalination and Water Treatment 2010, 22: 78-86.

62.Wenting Cheng, Zhibao Li. Nucleation kinetics of nesquehonite (MgCO3·3H2O) in the MgCl2-Na2CO3 system. Journal of Crystal Growth 2010, 312: 1563-1571.

63.Tiechui Yuan, Junfeng Wang, Zhibao Li. Measurement and modelling of solubility for calcium sulfate dihydrate and calcium hydroxide in NaOH/KOH solutions. Fluid Phase Equilibria 2010, 297: 129-137.

2009年

64.Jiayu Ma, Zhibao Li, Yi Zhang, George P. Demopoulos. Desilication of sodium aluminate solution by Friedel’s salt (FS:3CaO·Al2O3·CaCl2·10H2O). Hydrometallurgy 2009, 99: 225-230.

65.Wenting Cheng, Zhibao Li. Precipitation of nesquehonite from homogeneous supersaturated solutions. Crystal Research and Technology 2009, 44(9): 937-947.

66.Wenting Cheng, Zhibao Li, George P. Demopoulos. Effects of Temperature on the Preparation of Magnesium Carbonate Hydrates by the Reaction of MgCl2 with Na2CO3 at 273-363K. Chinese Journal of Chemical Engineering 2009, 17(4): 661-666.

67.Mei Dong, Zhibao Li, Jianguo Mi, George P. Demopoulos. Solubility and Stability of Nesquehonite (MgCO3·3H2O) in mixed NaCl + MgCl2, NH4Cl + MgCl2, LiCl, and LiCl + MgCl2 Solutions. Journal of Chemical & Engineering Data 2009, 5 (11): 3002-3007.

2008年

68.Mei Dong, Wenting Cheng, Zhibao Li, George P. Demopoulos. Solubility and stability of nesquehonite (MgCO3-3H2O) in NaCl, KCl, MgCl2, and NH4Cl solutions. Journal of Chemical & Engineering Data 2008, 53: 2586-2593.

69.Yong Wang, Zhibao Li, George P. Demopoulos. Controlled precipitation of nesquehonite by the reaction of MgCl2 with (NH4)2CO3 at 303K. Journal of Crystal Growth 2008, 310: 1220-1227.

70.George P. Demopoulos, Zhibao Li et al. New technologies for HCl regeneration in chloride hydrometallurgy. ERZMETALL 2008, 61(2): 89-98.

71.Yan Liu, Zhibao Li, Jianguo Mi, Chongli Zhong. Modeling of aqueous electrolyte solutions based on primitive and first-order Mean Spherical Approximation. Industrial & Engineering Chemistry Research 2008, 47: 1695-1701.

2007年

72.Zhibao Li, George P. Demopoulos. Speciation-based chemical equilibrium model of CaSO4 solubility in the H + Na + Ca + Mg + Al + Fe(II) + Cl + SO4 + H2O system. Industrial & Engineering Chemistry Research 2007, 46: 6385-6392.

2006年

73.Zhibao Li, George P. Demopoulos. Model-based construction of calcium sulfate phase-transition diagrams in the HCl-CaCl2-H2O system between 0 and 100 C. Industrial & Engineering Chemistry Research 2006, 45(13): 4517-4524.

74.Zhibao Li, George P. Demopoulos. Development of an improved chemical model for the estimation of CaSO4 solubilities in the HCl-CaCl2-H2O system up to 100 C. Industrial & Engineering Chemistry Research 2006, 45(9): 2914-2922.

75.Zhibao Li, George P. Demopoulos. Effect of NaCl, MgCl2, FeCl2, FeCl3, and AlCl3 on Solubility of CaSO4 Phases in Aqueous HCl or HCl + CaCl2 Solutions at 298 to 353 K. Journal of Chemical & Engineering Data 2006, 51(2): 569-576.

2005年

76.Zhibao Li, George P. Demopoulos. Solubility of CaSO4 phases in aqueous HCl + CaCl2 solutions from 283 K to 353 K. Journal of Chemical and Engineering Data 2005, 50(6): 1971-1982.

2002年

77.Zhibao Li, Lu, Benjamin C.-Y. Prediction of interfacial tension between an organic solvent and aqueous solutions of mixed-electrolytes. Fluid Phase Equilibria 2002, 200: 239-250.

2001年

78.Zhibao Li, Lu, Benjamin C.-Y. On the prediction of surface tension for multicomponent mixtures. Canadian Journal of Chemical Engineering 2001, 79: 402-411.

79.Zhibao Li, Lu, Benjamin C.-Y. A molecular model for representing surface tension for polar liquids. Chemical Engineering Science 2001, 56: 6977-6987.

80.Zhibao Li, Lu, Benjamin C.-Y. Surface tension of aqueous electrolyte solutions at high concentrations-representation and prediction. Chemical Engineering Science 2001, 56: 2879-2888.

2000年

81.Zhibao Li, Lu, Benjamin C.-Y. Excess molar enthalpies of the ternary mixture: 2,2,4-trimethylpentane +cyclohexane + n-octane. Thermochimica Acta 2000, 343: 43-48.

1999年

82.Zhibao Li, Yigui Li, Jiufang Lu. Surface tension model for concentrated electrolyte aqueous solutions by Pitzer equation. Industrial & Engineering Chemistry Research 1999, 38: 1133-1139.

1998年

83.Zhibao Li, Shiquan Shen, Meiren Shi. Prediction of the surface tension of binary and multicomponent liquid mixtures by the UNIFAC group contribution method. Thermochimica Acta 1998, 169: 231-238.

84.Zhibao Li, Jiufang Lu, Yigui Li. A statistical thermodynamic model of vapor-liquid interfacial tension for liquid mixtures at high pressure. Chinese Journal of Chemical Engineering 1998, 6: 257-263.

85.Chunxi, Li, Zhibao Li, Yigui Li. A thermodynamic model for calculating the surface tension of pure liquids and liquid mixtures. Tsinghua Science and Technology 1998, 3: 1029-1034.

1997年

86.Yongqi Hu, Zhibao Li, Jiufang Lu, Yigui Li, Yong Jin. A new model for surface tension of binary and ternary liquid mixtures based on Peng-Robinson equation of state. Chinese Journal of Chemical Engineering 1997, 5: 193-199.

主要专利

[1]李志宝,张妍,李赓,金仁涛. 一种蛇纹石和/或橄榄石的碱法处理方法,中国发明专利,专利号:2014100362939.

[2]李志宝,李赓. 利用七水硫酸亚铁制备四水氯化亚铁、氧化铁红和硫酸的盐酸循环法,中国发明专利,专利号:2014100232846.

[3]李志宝,曾澜沐. 一种利用二水氯化镁性质制备无水乙醇的方法. 中国专利,申请号:2013103923201

[4]李志宝,张妍,李赓. 一种蛇纹石和/或橄榄石的碱法处理方法. 中国专利,申请号:201410036293.9, 2013

[5]李志宝,曾艳. 一种利用碳酸氢钠控制过饱和度生产沉淀二氧化硅的方法. 中国专利,申请号: 201310382894.0, 2013.

[6]李志宝,李赓. 一种稀硫酸浓缩除杂的工艺方法. 中国专利,申请号:201210106955.6, 公布号:CN102633238A, 2012.

[7]李志宝,张妍. 一种利用蛇纹石制备氧化镁、镍、钴和白炭黑的方法. 中国专利,申请号:201210179818.5, 2012.

[8]李志宝,张妍. 一种采用Friedel盐或Kuzel盐除去水溶液中有害阴离子的方法. 中国专利,申请号:201210231178.8, 2012.

[9] 李志宝,高文成. 一种以粉煤灰为原料氯化亚铁诱导结晶制备六水氯化铝的方法. 中国专利,申请号:201210237836.4, 2012.

[10]李志宝,高文成,王均凤. 一种综合利用钾长石生产钾肥和氧化铝的方法. 中国专利,申请号:201010590230.X, 公开号:CN 102531710 A, 2010.

[11]李志宝,王均凤. 一种通过碳铵循环法经三水碳酸镁生产高纯氧化镁的方法. 中国专利,申请号:201010562109.6, 2010.

[12]李志宝,王道广. 一种通过制备六水合氯化铵镁复盐回收氯化铵的方法. 中国专利,申请号:201010108996.X, 2010.

[13]李志宝,孙顺平. 一种建筑材料及利用钛白废硫酸制备半水硫酸钙的方法. 中国专利,申请号:201110085646.0, 2011.

[14]李志宝,马家玉,王英军. 一种用水滑石除去水溶液中金属离子的方法. 中国专利,申请号:201010239598.1, 2010.

[15]李志宝,王均凤. 一种制备电解镁用无水氯化镁的方法. 中国专利,申请号:201010108988.5,2010.

[16]李志宝,王勇. 一种使用连续结晶法制备三水碳酸镁的方法. 中国专利,申请号:201010119370.9, 2010.

[17]李志宝,马家玉. 一种含硅的铝酸钠溶液深度脱硅的方法. 中国专利,申请号:200910084484.1, 2009. 公开号:CN 101891227 A.

[18]李志宝,肖清贵. 从低品位一水硬铝石型铝土矿中脱除二氧化硅. 中国专利,申请号:200910081559.1, 2009.

[19]李志宝,祁宏波,邵平平. 一种利用苦卤与碳酸盐制备氧化镁的方法. 中国专利,申请号:200910076545.X,2009.

[20]李志宝,张妍. 一种利用氯化盐浸取钼精矿提纯二硫化钼的方法. 中国专利,申请号:200910087262.5,2009.

[21]李志宝,王道广,程文婷. 以碳酸镁水合物为中间体生产氧化镁并联产氯化铵的方法. 中国专利,申请号:200910091752.2, 2009.

[22]李志宝,程文婷. 一种以三水碳酸镁为中间体制备氧化镁的方法. 中国专利,申请号:200810114987.4, 2008.

[23]李志宝,肖清贵. 在硫酸介质中分解氯化铵制备盐酸和硫酸铵的方法. 中国专利,申请号:200810056435.2,2008.

[24]李志宝,王勇. 一种使用碳酸铵从含氯化镁卤水中制备三水碳酸镁的方法. 中国专利,申请号:200710064243.1, 2007.